Select database:
\c database_name
Create user with password:
create user someuser password 'somepassword';
Grant privileges on DB:
GRANT ALL PRIVILEGES ON DATABASE mydb TO someuser;
Grant privileges on all tables in particular DB:
GRANT ALL PRIVILEGES ON ALL TABLES IN SCHEMA public TO someuser;
Grant privileges on all sequences:
GRANT USAGE, SELECT ON ALL SEQUENCES IN SCHEMA public TO someuser;